The Incredible Shrinking Water Bottle
UPDATE: Primo's VP of Marketing Responds to Incredible Shrinking Water Bottle
Reader David wrote in to show us the transformation of his incredible shrinking water bottle. The bottles used by Primo bottled water are made from plant by-products which degrade easily compared to normal plastic, making them more eco-friendly. However, as David found out, they shrink to nearly half their size when exposed to sunlight and the heat from inside a car which could easily result in a watery mess. David's letter and photo, inside...
Editors,
I recently purchased a case of Primo bottled water. Like other products,
it's trying to a niche. Their spin is that the plastic in the bottle is
made from plants, not crude oil. Additionally, they claim the water tastes
just as good as the national brands. BUT the thing you aren't told is that
the bottle shrinks!I left a bottle in my car while I was at work (I park in an open lot). When
I left work and got into my car, I noticed that the bottle was half its
original size. The bottle shrank after a few hours under the Houston sun.
Perhaps plastic made from corn by-products is not as durable as plastic
from petroleum. Whatever it is, I am concerned. If the bottle was full and
it shrank, it could have exploded from the pressure. Or it could have
gushed out as I was opening it. Because the plastic is so sensitive to 100
degree heat, it doesn't serve its purpose very well. And, this probably
means that toxins could be leaking out from the plastic.Buyer beware!
I have enclosed a picture that compares the original bottle with the
shrunken version.Thank you,
David
Degradable bottles seem like a good idea, we just don't want them degrading inside of our cars.
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Comments:
@doctor_cos: Holding a match to the bottom of a cup, the heat will disipate into the water and out into the air. Locked inside a hot car, the car, bottle, and water will all eventually reach the same temperature, the heat will have nowhere to go, and the end result will be the same.
@Git Em SteveDave is a poor substitute for LindsayJoy: Heck, here in MI I've had cans burst open in my car. Happened 3 weeks ago. Not fun.
Right. Water is only very slightly compressible. So how could that bottle have shrunk that much without bursting or at least leaking out the top? And why didn't the threaded section shrink? Skeptical...
a few years back, there was a water bottling company in colorado who made water bottles using bioplastics. publix picked them up and i bought a few 6-packs for a few weeks until i guess they went under. anyhow, there was a warning label on those bottles stating that you had to keep the bottles COOL. the corn-based bioplastic was designed to decompose when applied with around 350 degrees fahrenheit. the only problem is i don't see this warning stated obviously on primo's website and they seem to have this problem too. this has nothing to do with a poor product, but more to do with poor labeling and not educating your consumers on the limits of the container.
And now we see first hand the fallacy of "eco-friendly" (self?)disposable packaging. It's generally more expensive, you can't store it for long periods of time, you can't even leave it in your car. There's no expiration date or instructions on safe use or storage of the product (probably because the manufacturer doesn't know either).
Can't we come up with something that takes a more reasonable amount of time to break down? I don't know, two years maybe? Five? Certainly that would be sufficient compared to hundreds (thousands?) of years for normal plastics.
You would also have to take in consideration the amount of energy it would take to heat the water. I would think you would also have to heat the water to the same temp to melt the bottle. You can do a simple experiment yourself. Take and suspend a piece of copper tubing (or any metal for that matter) in a piece of paper. You would hold each edge of the paper and the tubing would be in the middle. You would have a tear drop shape in profile. Then take a flame and place it under the tubing. The paper will blacken, but it won't burn. Not until you reach the melting point of the metal.
My guess is the water bottle was nearly empty-you can see the water level in the small bottle. I don't think this isa trick either-if you look closely, the base of the shrunk bottle is wider than the middle-I've never seen a bottle sold like that.
As for the threaded section, it may have been a different plastic. At the least, it's a thicker plastic. Come to think of it, that would explain why the base didn't shrink as much either.
@TheAlphateam: not necessarily the melting point. Once the metal heats to the flash point f the paper, it'll go.
@basket548: Umm...on the basis that the bottle has heated to the point where it's becoming severely deformed. That's the first thing I thought of when reading this...who cares about water all over your upholstery, I'd be worried about what the bottle might be leaching into my water.
You don't need 100% scientific proof here, just a reasonable dose of caution...
@NotATool:
Still no basis. Even a reasonable dose of caution doesn't seem to indicate that. What manufacturer would EVER release a product that leaks anything remotely harmful when subject to normal environmental conditions?
Also, just because something shrinks and 'deforms' doesn't mean that it's leaking something dangerous. Think of it as a plastic balloon. Same exact concept.
"What manufacturer would EVER release a product that leaks anything remotely harmful when subject to normal environmental conditions?"
Google "Nalgene" and "BPA"
@colinjay:
Good point, however, BPA is far from a proven, well, anything. Everything and its mother is getting linked to cancer these days, and the point I was trying to make was that no manufacturer would knowingly release a product (especially one marketed as 'organic'-like) with that sort of an issue.
Bottles like that are made by warming the plastic, then inflating it within a bottle-shaped mold. When the plastic cools, it keeps the shape of the mold. But it's under some of tension; heat it a bit and it will contract. You can make regular two-liter bottles shrink the same way, by heating them with steam from a tea kettle.
I agree that if the bottle were full of water, it wouldn't have shrunken like that, though it might have deformed a bit.
@basket548: I agree. Since the main purpose of the plastic is to bidegrade in this way, I'm guessing it was designed so it wouldn't leach poison into the environment. Plus, I'm willing to bet that this pretty common scenario was covered during the product testing.
This is a common effect in bottles that a made from blow-molding. The bottle starts out as a plastic tube called a parison, which looks like a test tube. It is literally blown out with air pressure into a bottle shaped mold. The stretching, as the bottle takes its shape, will orient the polymer molecules in the plastic. The bottle is cooled, which freezes the polymer molecules in place. If you raise the temperature the polymers unfreeze and return to their original position, making the bottle return to its original shape.
The screw cap part doesn't shrink because it was never stretched in the blow-molding process. You can try this yourself by holing a match under an empty water or soda bottle. Any bottle with the recycle code of "1 PET" of "1 PETE" should shrink some under heat.
The newer plastic likely isn't biodegrading but simply undergoing the same process at a lower temperature.
@Git Em SteveDave is a poor substitute for LindsayJoy:
Sorry... but there's no way a can would explode in a hot car. Worst case is the dent in the bottom of the can (also known as the "kick" or "punt") would be pushed out. That's exactly what it's designed to do. I've had full cans in a car at 150+ degrees and they we undamaged.
@chrisjames: and to the author:
Because the plastic is so sensitive to 100 degree heat, it doesn't serve its purpose very well. And, this probably means that toxins could be leaking out from the plastic.
MmmmHmmm. This belief is based on what, exactly? Do you even know what the bottle is made of that might be toxic?@
href="#c6857155">colinjay: BPA in cans and bottles in not unsafe. Both the FDA and Health Canada have shown (using science, of all things) that there is no danger presented by the BPA in cans and bottles.
Are you sure they had not already been damaged. If a can has already been dropped and the can dented, they can then be prone to exploding when heated. But an undamaged can should do that.
@Ubermunch: Sorry... but there's no way a can would explode in a hot car.
I've seen the aftermath of a heat-related soda can explosion in the Arizona desert. [mythbusters-wiki.discovery.com] has stories of a few more.
We have a number of coffee shops here that serve their cold to-go drinks in corn-based plastic cups. They shrink like this when you leave them in the car.
It's still better than oil-based plastics, so if you want a bottle to hold onto that won't shrink, buy a Sigg bottle.
My only complaint is that I can't recycle these cups (number 7) and they just get tossed if you don't have a compost disposal bin around (which is basically everywhere).
@Ubermunch: Well, speaking from personal experience, for which I had a stain on the roof of my car until I got rid of it, yes, they can. The can in my question HAD popped out the bottom. It then failed on the top seam/lip of the can, which dented out as well. Given my story, the other one below mine, and the link above, I am going to say that a can CAN burst/explode in a heated car. Now I believe my can was a Diet Coke, so if anyone can further expand on their stories, maybe a certain kind of soda has a propensity to crack. Now that I think about it, Diet Coke seems to be very energetic, especially when combined w/Mentos.
@Ubermunch
A can of soda can most definitely explode in a hot car. I left a sealed can of Sprite near the rear window of a car in 90+ degree heat in Toledo, OH a few years ago. Walking back to the car, I noticed that it looked all "foggy" inside. Of course, it was really that the entire inside of my car was coated in sugar-water, some of which had browned/carmelized and dried to the ceiling, carpet, etc. Not fun.
The can looked like it had been torn open very violently, length-wise. The bottom indentation was pushed out as well.






















There are other concerns with biopolastics as well - many of them only degrade in very specific conditions which require special facilities to process them. It's not like you can just toss them into your compost or the landfill or whatever and they'll break down on their own.